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Doll Repaint
This was Barbie before I started.
Original Barbie
The First thing I did was remove her "makeup".  I tried non-acetone nail polish remover but couldn't get all the paint off of her, especially her lips so I went and got pure acetone.  Kudos to Stroudsburg Beauty Supply next to AC Moore for the acetone.  Anyway, the acetone worked like a champ, then I bathed her face in a baking soda wash so the vinyl wouldn't get ruined from the acetone and rinsed her hair a bit to be sure there was nothing in that.

Now to start with her hair.  I decided not to reroot on the first doll so I had to color.  I was going for a goth look so I wanted dark, black hair on my blond Barbie.  After looking at the options I settled on acrylic paint.  I started with Liquitex Basic Ivory Black since they were out of Mars Black at the local AC Moore.  I covered her body with a plastic bag and covered her face with plastic wrap to protect her from getting painted while doing her hair.  I put on plastic gloves myself.  I added water to the paint so it was almost an ink-like consistency then used a foam paint brush to coat her hair.  I used a fine tooth comb to work it through her hair from the scalp to the ends. This is her after her first coat of paint.
Barbie Painted Hair
After letting her sit a bit, her hair looked a bit grayish so I did another coat using Apple Barrel black acrylic undiluted as it's a thinner craft paint.  I don't know that the paint color was bad she probably just needed a second coat since trying to cover that blond with black was likely to need more than 1 coat.  I also gave up on the gloves during the process as I had to keep combing her hair periodically as it dried all afternoon.  The paint washed right off my hands with soap and water easily anyway.  

Ok, Once the paint dried, I really didn't like the stiff, dull looking painted hair.   Not sure I would do hair "painting" again.  I'd like to get some yard sale dolls and try dying the hair with kool-aid or rit dye.  I'm starting the face painting now.  This should be fun...